最近の原著論文リスト: Strike while the iron is hot; Time flies like an arrow.
H. Teramoto, S. Sakaguchi, Enantioselective catalytic hydrosilylation of propiophenone with a simple combination of a cationic iridium complex and a chiral azolium salt, J. Organomet. Chem., 875, 52-58 (2018).
Y. Nakano, S. Sakaguchi, Inversions in asymmetric conjugate addition reaction of cyclic enones catalyzed by the Cu/NHC-AgX system: Factors affecting the stereoselective formation of both enantiomers, J. Organomet. Chem., 846, 407-416 (2017).
Y. Manabe, K. Shinohara, H. Nakamura, H. Teramoto, S. Sakaguchi, Chiral N-heterocyclic carbene iridium catalyst for the enantioselective hydrosilane reduction of ketones, J. Mol. Cat. A: Chem., 421, 138-145 (2016).
K. Matsumoto, Y. Nakano, N. Shibata, S. Sakaguchi, Enantioselectivity switch in copper-catalyzed conjugate addition reactions under the influence of a chiral N-heterocyclic carbene-silver complex, RCS Adv., 6, 7755-7759 (2016).
S. Kamihigashi, N. Shibata, S. Sakaguchi, Cu-catalyzed asymmetric conjugate addition of dialkylzincs to enones using (±)-trans-1,2-cyclohexanediamine-based bis(NHC) derived from L-leucinol, Synlett, 25, 2933-2937 (2014).
J. Kondo, A. Harano, K. Dohi, S. Sakaguchi, C2-symmetric functionalized azolium salt from serine ester for Cu-catalyzed asymmetric conjugate addition reaction, J. Mol. Cat. A: Chem., 395, 66-71 (2014).
K. Shinohara, S. Kawabata, H. Nakamura, Y. Manabe, S. Sakaguchi, Enantioselective Hydrosilylation of Ketones Catalyzed by a Readily Accessible N-Heterocyclic Carbene-Ir Complex at Room Temperature, Eur. J. Org. Chem., 2014(25), 5532-5539 (2014).
M. Yoshimura, R. Kamisue, S. Sakaguchi, Synthesis of Ru(II) complexes containing N-heterocyclic carbenes functionalized with secondary donor groups: Catalytic activity towards enantioselective transfer hydrogenation, J. Organomet. Chem., 740, 26-32 (2013).
坂口 聡,キラルなアゾリウム塩による銅触媒不斉共役付加反応,有合化71(4),319-329 (2013). [invited review]
H. Shirasaki, M. Kawakami, H. Yamada, R. Arakawa, S. Sakaguchi, Highly tunable anionic tethered N-heterocyclic carbene of Pd(II) complexes for asymmetric allylic alkylation reaction, J. Organomet. Chem., 726, 46-55 (2013).
K. Dohi, J. Kondo, H. Yamada, R. Arakawa, S. Sakaguchi, Functionalized N-Heterocyclic Carbene Ligands for Dual Enantioselective Control in the Cu-Catalyzed Conjugate Addition of Dialkylzinc Compounds to Acyclic Enones, Eur. J. Org. Chem., 2012(36), 7143-7152 (2012). [Synfacts 2013, 9, 183.]
N. Shibata, M. Yoshimura, H. Yamada, R. Arakawa, S. Sakaguchi, Hydroxy-amide-functionalized Azolium Salts for Cu-catalyzed Asymmetric Conjugate Addition: Stereocontrol Based on Ligand Structure and Copper Precatalyst, J. Org. Chem., 77(8), 4079-4086 (2012).
M. Yoshimura, N. Shibata, M. Kawakami, S. Sakaguchi, Ligand design for dual enantioselective control in Cu-catalyzed asymmetric conjugate addition of R2Zn to cyclic enone, Tetrahedron, 68(17), 3512-3518 (2012). [invited paper]
S. Kawabata, H. Tokura, H. Chiyojima, M. Okamoto, S. Sakaguchi: Asymmetric Hydrosilane Reduction of Ketones Catalyzed by an Iridium Complex Bearing a Hydroxyamide-Functionalized NHC Ligand, Adv. Synth. Catal., 354(5), 807-812 (2012).
H. Chiyojima, S. Sakaguchi: Iridium complex bearing a chiral hydroxy-amide functionalized N-heterocyclic carbene: a catalyst precursor for asymmetric transfer hydrogenation, Tetrahedron Lett., 52(20), 6788-6791 (2011). [化学工業日報, 2011.12.8.]
R. Kamisue, S. Sakaguchi: Synthesis and Characterization of Amide-Functionalized N-Heterocyclic Carbene-Pd Complexes, J. Organomet. Chem., 696(9), 1910-1915 (2011).
A. Harano, S. Sakaguchi: A new C2-symmetric azolium compound for Cu-catalyzed asymmetric conjugate addition of R2Zn to cyclic enone, J. Organomet. Chem., 696(1), 61-67 (2011). [invited paper]
N. Shibata, M. Okamoto, Y. Yamamoto, S. Sakaguchi: Reversal of Stereoselectivity in the Cu-Catalyzed Conjugate Addition Reaction of Dialkylzinc to Cyclic Enone in the Presence of a Chiral Azolium Compound, J. Org. Chem., 75(16), 5705-5015 (2010). [化学工業日報, 2010.7.22.]
Y. Shimakawa, T. Morikawa, S. Sakaguchi: Facile route to benzils from aldehydes via NHC-catalyzed benzoin condensation under metal-free conditions, Tetrahedron Lett., 51(13), 11786-1789 (2010). [Top-25 most cited articles]
S. Sakaguchi, M. Kawakami, J. O'Neill, K.S. Yoo, K.W. Jung; Tridentate, anionic tethered N-heterocyclic carbene of palladium complex, J. Organomet. Chem., 695(2), 195-200 (2010).
K. S. Yoo, J. O'Neill, S. Sakaguchi, R. Giles, J. H. Lee, K. W. Jung: Asymmetric Intermolecular Boron Heck-Type Reactions via Oxidative Palladium(II) Catalysis with Chiral Tridentate NHC-Amidate-Alkoxide Ligands, J. Org. Chem., 75(1), 95-101 (2010). [releated manuscript: Org. Lett. 2007, 9, 3933; 有合化, 2008, 66, 175.]
M. Okamoto, Y. Yamamoto, S. Sakaguchi; A new approach to switching of enantioselectivity in NHC-Cu-catalyzed conjugate addition of alkylzincs to cyclic enones, Chem. Commun., (47), 7363-7365 (2009).
S. Sakaguchi, K.S. Yoo, J. O'Neill, J.H. Lee, T. Stewart, K.W. Jung; Chiral Palladium Complexes Possesing a Tridentate N-Hetreocyclic Carbene Amidate Alkoxide Ligand: Access to Oxygen-Bridging Dimer Structures, Angew. Chem. Int. Ed., 47(48), 9326-9329 (2008).
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Last Modified 09/13/2018, send comments to satoshi@kansai-u.ac.jp